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Nov 1975

Volume 12, Issue 6, pp. 1121-1436


Abstract: Strategies in lithography

Donald R. Herriott

J. Vac. Sci. Technol. 12, 1121 (1975); http://dx.doi.org/10.1116/1.568472 (2 pages)

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The functional complexity of integrated circuits has been doubling each year for many years and can be expected to continue increasing at that rate for the forseeable future. The feasibility of larger devices with smaller features is well illustrated by papers in this issue. The motivation to continue this trend is the high cost of interconnecting smaller units and the repeated denonstration that the more complex device soon costs less than the multiple‐chip equivalent. The smaller feature devices also provide faster response and consume less power.
Optical systems: Optical techniques for fabricating devices are generally limited to ≳5 μm linewidths in practical production by the diffraction effects. While contact printing can achieve <2 μm resolutions, the defects caused by contacting the wafer limit the yields, especially when device area is large. Projection printing can give 2‐μm features when small areas are exposed at one time with individual focus correction.
Alternate wavelengths: Electron beams or soft x rays promise the necessary performance in the future because their shorter wavelength avoids significant diffraction limitations.
The ELIPS electron‐image system uses a photocathode coated on an optical master with uv illumination from behind to provide a patterned source of electrons that can be imaged to expose a Si wafer. The parallel exposure of the whole pattern requires but a few seconds. Substrate flatness error may cause significant distortion of the patterns. Techniques have been described for realignment and equipment has been available, but no commercial use of the system has developed.
A step‐and‐repeat electron imaging system has been described in which an electron‐transparent mask is reduced onto the electron‐resist‐coated substrate. Such a system would require time for the stepping, alignment, and exposure of each chip on the substrate, and the electron‐transparent mask would be difficult to fabricate, fragile in construction, and subject to distortions from heating in the electron beam.
Soft x rays may be used for proximity printing of masks having Au features on transparent substrates onto x‐ray‐resist‐coated wafers. One system requires long exposures with 8‐Å radiation through Si substrate masks onto PMMA resists, but achieves good resolution and stability. Another uses 4‐Å radiation with Mylar substrates and Be windows to achieve shorter exposures in air onto special x‐ray resists. Further development will be required before these systems are useful.
While no company can develop all of these systems, it is economically important to each that they have easy access to the most successful technology. Pattern generation: Electrons can be used to generate a pattern as well as to image it onto a wafer. Electrons can be imaged to a point and that point scanned over the resist‐coated substrate and modulated to serially expose the pattern. Such systems are pattern generators in that they expose a hard‐copy pattern from a software description. Many research systems have been constructed using a vector scan of the electron beam to expose each feature in the pattern of a single chip. The substrate is then moved, realigned at the next chip location, and the next pattern written. The aberrations of the electron‐optical system limit the field to a few millimeters for a 1‐μm address size and smaller for the 0.1‐ or 0.2‐μm address commonly used. This limits the device size or requires butting of separate fields which is satisfactory for exploratory work. Settling time is required after long deflection moves with the vector scan, but exposure time is reduced for low‐density patterns. Many exploratory devices have been fabricated by directly exposing resist‐coated substrates using this technique, although the time required for serial exposure is generally too long for economical commercial production.
EBES: An electron‐beam exposure system (EBES) was developed at Bell Laboratories because it is necessary as a pattern generator for use in making masks for various printing methods as well as for direct device exposure. It was designed to provide economical performance at the half‐micron address structure which is important at this time, although it can be modified gracefully to provide higher resolution as required. It has been used to make masks and direct exposures for a year with better performance and at lower cost than alternate optical systems.
The system uses a very small field of electronic deflection combined with a continuously moving servo table. The small (140‐μm) deflection field allows maximum brightness, negligible aberrations, and excellent dimensional control. Laser interferometers measure errors in the table position that are corrected by deflection of the electron beam to compensate for vibrations, distortions, and slow table response. The feedback system provides the deflection speed of electron deflection, the field size of mechanical table motions, and the accuracy of laser interferometers.
A raster scan is used within the 140‐μm‐square field in order to minimize the deflection requirements and ease the problem of data handling so that 10‐MHz data rates can be used. The pattern information from an input tape is decoded and stored in memory so that it can be read out repeatedly for each of the chips in the usual pattern. Only a 128‐μm‐wide stripe of the chip is stored at one time to minimize the memory requirement, and this is written on each chip along a serpentine path on the substrate before the next stripe is decoded and exposed adjacent to the first. The system periodically is used in the electron microscope mode to locate a registration mark to cancel accumulated drift. Realignment of sequential levels in directly exposed devices is accomplished by finding three registration marks and distorting the pattern to exactly fit at these points.
The system will write patterns at a 1 cm2/min rate on Si wafers or chrome mask substrates. A usual 2‐in. (5.08‐cm) wafer will thus require about 20 min, including test patterns. A number of other papers in this issue will describe portions of the system in detail and its application to mask making and direct wafer exposure. A more complete general description is published in the special issue of the IEEE Transactions on Electron Devices on device lithography (July 1975).
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams

Synchrotron radiation as a new tool within photon‐beam technology

S. Doniach, I. Lindau, W. E. Spicer, and H. Winick

J. Vac. Sci. Technol. 12, 1123 (1975); http://dx.doi.org/10.1116/1.568473 (5 pages) | Cited 7 times

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Synchrotron radiation is now playing an increasingly important role in recent developments of new light sources. Synchrotron light emitted from a relativistic electron beam has a radiation pattern which makes it a unique source. The advantages with this type of radiation can be summarized as (a) continuous spectrum extending from the ir to the x‐ray region, (b) strongly polarized, (c) highly collimated, (d) pulsed structure allowing time‐resolution spectroscopy, and (e) high intensity making feasible the use of monochromators with narrow band pass. The Stanford Synchrotron Radiation Project has been in operation since May 1974 as a U.S. National Facility for uv and x‐ray research in many disciplines using the radiation from the storage ring SPEAR at the Stanford Linear Accelerator Center. The radiation spectrum is characterized by the critical energy which varies as E3 (E=electron‐beam energy) and is 11 keV for E=4 GeV. Useful flux is available out for approximately five times the critical energy. Five monochromators now share the beam run and cover the entire wavelength region from the visible to the hard x‐ray region. Several experimental groups are involved in research programs including (a) uv and x‐ray photoelectron spectroscopy, (b) optical reflectance and transmission studies, (c) soft x‐ray absorption and extended x‐ray absorption fine structure (EXAFS) studies, (d) low‐angle scattering studies of certain biological materials, and (e) x‐ray diffraction studies of protein crystals and other materials.
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07.85.-m X- and γ-ray instruments
07.60.Rd Visible and ultraviolet spectrometers
42.72.-g Optical sources and standards

Ionized‐cluster beam deposition

T. Takagi, I. Yamada, and A. Sasaki

J. Vac. Sci. Technol. 12, 1128 (1975); http://dx.doi.org/10.1116/1.568474 (7 pages) | Cited 23 times

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We describe a form of deposition in which material is vaporized in a crucible and the vapor then ejected through a fine nozzle at the focus of an electron beam in a high vacuum. The vapor, on emerging from the nozzle, is partially condensed into clusters that are ionized by electron bombardment and then accelerated onto the substrate. The deposited films show good adhesion and large crystallite size. Examples include the deposition of Cu onto glass, Si onto Si, and ZnS onto NaCl.
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81.20.-n Methods of materials synthesis and materials processing
68.55.-a Thin film structure and morphology

Electron‐projection microfabrication system

M. B. Heritage

J. Vac. Sci. Technol. 12, 1135 (1975); http://dx.doi.org/10.1116/1.568475 (6 pages) | Cited 15 times

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An electron‐optical analog of a photon‐optical projection camera is described. The system is designed to meet the requirements of future memory technology with submicrometer resolution over a chip size of several millimeters. A self‐supporting foil mask is illuminated by electrons and magnetically imaged onto a wafer with a 10×reduction in size. This paper describes the electron optics required for a high‐resolution large‐field performance. Particular emphasis will be placed on the means for reducing the third‐order aberrations of the magnetic projection lenses. The limitations imposed by the unavoidable aberrations of the condenser system are also discussed. The performance of the system is illustrated by reference to results obtained by exposing test patterns.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams

Electron‐beam projection systems with compensated chromatic field aberrations

H. Koops and W. Bernhard

J. Vac. Sci. Technol. 12, 1141 (1975); http://dx.doi.org/10.1116/1.568476 (5 pages)

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Microminiaturization for the production of modern large‐scale integrated circuits requires electron‐optical devices capable of recording more than 10 000 resolved lines per frame at a resolution of 0.1 μm. Magnetic demagnifying electron‐projection systems with compensated chromatic field aberrations are capable of recording up to 10 000 lines per frame. In our system, the optimum aperture for a maximal number of lines per frame depends only on the coefficients of field curvature, isotropic and anisotropic astigmatism, and on the electron wavelength. A theoretical expression for the maximal number of lines per frame indicates that the number of lines can be increased by using a small demagnification factor and by increasing the dimensions of the electron‐projection system.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams

Design and optimization of magnetic lenses and deflection systems for electron beams

E. Munro

J. Vac. Sci. Technol. 12, 1146 (1975); http://dx.doi.org/10.1116/1.568477 (5 pages) | Cited 4 times

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Methods are described for computing the optical properties of any combination of magnetic lenses and deflection yokes, including the most general case in which the lens and deflector fields may be physically superimposed. These techniques can handle either toroidal or saddle deflection yokes, wound on either nonmangetic of ferromagnetic formers, and can handle cases where the magnetic materials of the lenses directly influence the deflection fields. The basic program for calculating the properties of any given lens and deflection system has been combined with an optimization program, which systematically searches (subject to given physical constraints) for the arrangement which minimizes the deflection aberrations for any specified field size and aperture angle. Illustrative computed results are presented. It appears that conventional postlens single‐deflection systems can have better properties than conventional prelens double‐deflection systems. However, the performance of double‐deflection systems can be improved dramatically by placing the second yoke inside the lens and rotating it relative to the first yoke. An arrangement has been found, which, at the corners of a 5×5‐mm deflection field with 0.005‐rad aperture and 1 in 104 beam voltage ripple, produces a total aberration disk of 0.45 μm before dynamic corrections, or 0.15 μm after dynamic corrections. The properties of in‐lens single‐deflection systems have also been investigated. Such systems offer the possibility, for the same operating conditions as quoted above, of producing a total aberration disk of less than 0.2 μm after dynamic corrections. By introducing a ’’predeflection coil’’ before the main deflection coil, this value can be reduced to less than 0.1 μm.
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41.75.Fr Electron and positron beams
29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators

Abstract: Low‐aberration deflection system for microfabrication

G. Owen and W. C. Nixon

J. Vac. Sci. Technol. 12, 1151 (1975); http://dx.doi.org/10.1116/1.568478 (1 page)

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A theoretical design has previously been proposed for a low‐aberration magnetic deflection system.1 This has now been translated into practice. Specially shaped interleaved deflection coils have been constructed that give rise to low values of all the aberration coefficients except for distortion and field curvature. The latter aberration is corrected electrically. Since the sole effect of distortion is to destroy the linearity between coil excitation and beam deflection, no correction for this aberration has been incorporated at present. A combined electrical and mechanical centering procedure has been developed and implemented. The deflection system has been tested and found to increase the diameter of an on‐axis spot by a maximum of 1.2 μm over a 3×3‐mm working field at an angular aperture of 8 mrad. This compares well with the theoretically predicted value of 1.3 μm. The spot diameter has been taken as the 1% to 99% rise distance of the transmitted beam current as the spot was scanned across an edge.
The theoretical work has been extended to show that under certain conditions it is, in principle, possible to eliminate the noncorrectable aberrations completely.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
41.75.Fr Electron and positron beams

Design of fast deflection coils for an electron‐beam microfabrication system

K. Amboss

J. Vac. Sci. Technol. 12, 1152 (1975); http://dx.doi.org/10.1116/1.568479 (4 pages) | Cited 1 time

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The design of improved postlens deflection coils for electron‐beam microfabrication is described. These coils were made for use in a Cambridge Instrument Co. model S‐4 scanning‐electron‐microscope column. These new coils permit a 0.8‐nA 20‐kV beam to cover a 2‐mm‐square scan field with a theoretical resolution of 0.1 μm.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
07.78.+s Electron, positron, and ion microscopes; electron diffractometers
41.75.Fr Electron and positron beams

Aberrations and tolerances in a double‐deflection electron‐beam scanning system

M. G. R. Thomson

J. Vac. Sci. Technol. 12, 1156 (1975); http://dx.doi.org/10.1116/1.568480 (4 pages) | Cited 1 time

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A magnetic deflection system intended for use in an electron‐beam lithography instrument has been analyzed. The electron beam is to be scanned over a 0.3‐mm‐square field at a working distance of 15 mm and with a final lens convergence semiangle of 0.013 rad. The maximum allowed spot broadening is 0.05% of the side of the square (i.e., 0.15 μm) and the maximum distortion is half of this (0.075 μm). A system is proposed with a performance which substantially exceeds these requirements so some of the excess can be sacrificed in exchange for a larger tolerance of construction and alignment errors. Dynamic correction methods are not necessary. The system is constrained (by the dimensions of a final lens that had already been chosen) to fit within a cylinder 30 mm in diameter and 100 mm long. No magnetic material is used for the core of the deflection coils. A double‐deflection system was analyzed theoretically and the geometric and chromatic aberrations were calculated. The azimuthal positions of the conductors that are parallel to the electron‐beam axis are critical. To obtain best performance, the angles must be correct to within a degree, but to meet the above requirements an error up to 8° can be tolerated. The tolerance of off‐axis misalignment of the whole scanning system was estimated. For best performance the misalignment must not exceed ±0.25 mm, but in this application distances of up to ±2 mm can be tolerated. In the absence of errors, the system can scan over 1/30 rad (0.5 mm) square.
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07.78.+s Electron, positron, and ion microscopes; electron diffractometers
41.75.Fr Electron and positron beams
85.40.Bh Computer-aided design of microcircuits; layout and modeling

Abstract: Theory of lenslet interactions in a fly’s eye lens

K. J. Harte

J. Vac. Sci. Technol. 12, 1160 (1975); http://dx.doi.org/10.1116/1.568481 (1 page)

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In an electron‐optical fly’s eye lens, comprised of several parallel plates with arrays of aligned holes, the field at each lenslet is distorted by the fields of the surrounding lenslets. This interaction sets a limit on how closely packed the array can be (or how large the lenslet holes can be for a given spacing) and therefore has a direct bearing on performance. In this paper a method is developed for calculating the effect of the interaction for arbitrary lens geometry.
First, from the symmetry of the environment of each lenslet, Neumann boundary conditions are derived on the bounding polygon between lenslets. These boundary conditions are expanded in a Fourier‐perturbation series about the circle which is the zeroth harmonic of the polygon. Laplace’s equation is then solved within the bounding circle for each harmonic to first‐order in the perturbation theory, for example by numerical relaxation. Second‐ and higher‐order solutions can be similarly obtained if necessary. From the zeroth Fourier component of the resulting axial potential, Gaussian properties of the lenslet are obtained, along with the spherical aberration coefficient. The next nonvanishing harmonic (fourth for a square array of lenslets, sixth for an hexagonal array) determines a corresponding aberration coefficient, which describes the major effect of lenslet interactions on the focused spot. Higher‐order aberration coefficients are calculated from higher‐harmonic potentials, if needed.
Finally, as an example, the method is applied to a three‐element einzel lens with a square array of lenslets. Fourfold aberrations, which are the dominant interaction effect, are found to be significant if the hole diameter in the center element is greater than about 70% of the lenslet spacing, in rough agreement with experimental results. At this diameter such aberrations amount to roughly one tenth of the spherical aberration.
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29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
41.75.Fr Electron and positron beams

Advances in matrix‐lens technology

H. G. Parks and W. C. Hughes

J. Vac. Sci. Technol. 12, 1161 (1975); http://dx.doi.org/10.1116/1.568482 (4 pages) | Cited 1 time

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Recent improvements in matrix‐lens technology are reported in this paper. Previously, the lenslets have been of the three‐aperture einzel construction. An extensive computer study of three‐aperture einzel and two‐aperture immersion lenses has been made at the General Electric Research and Development Center. Calculations, based on data from this study, demonstrate significant electron‐optical advantages for two‐aperture immersion lenslets as opposed to three‐aperture einzel lenslets. Experimental data verifying the two‐aperture immersion‐ lenslet operation are presented. Application of the two‐aperture immersion matrix lens in a sealed tube environment is also presented and discussed.
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29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
41.75.Fr Electron and positron beams

Unipotential lens with electron‐transparent electrodes

N. D. Wittels

J. Vac. Sci. Technol. 12, 1165 (1975); http://dx.doi.org/10.1116/1.568483 (4 pages) | Cited 3 times

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This paper reports results of the first test of a unipotential electron lens whose end electrodes are electron‐transparent foils. This lens is unusual among electrostatic unipotential lenses in that it can have negative values for both its focal length and third‐order spherical aberration coefficient. Preliminary measurements of these quantities have been made on a foil lens and are compared with theoretical values. Some of the practical limitations in using foils as lens elements are considered, and a potential use for this lens as part of a spherical aberration corrected doublet is discussed.
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29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
41.75.Fr Electron and positron beams

Abstract: Electron gun for data storage micromachining

J. E. Wolfe

J. Vac. Sci. Technol. 12, 1169 (1975); http://dx.doi.org/10.1116/1.568484 (1 page) | Cited 1 time

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This paper describes an electron gun and associated electron optics developed to provide the capability for electron‐beam machining of high‐density patterns in metal surfaces for information storage. It is presented with two companion papers by A.B. El‐Kareh1 from the University of Houston and Lynwood Swanson2 from the Oregon Graduate Center. We omit certain aspects of the memory system such as analysis of the recording process and the readout considerations. Very briefly, to machine evaporatively at densities of 1010 bits/cm2 and at rates of 107 bits/sec requires a power density greater than 107 W/cm2 at voltages of 5000 V or less with careful selection of target material. Low voltage reduces the scattering range of electrons and high power density produces the high temperatures required for machining in the face of high rates of heat flow encountered with very small heated volumes.
The electron gun employs a heated field‐emission cathode capable of good angular confinement of emission and low energy spread. An operating temperature of 1800 K allows operation of the cathode in ambient pressures within the range of 10−7–10−8 Torr (10−5–10−6 Pa). The cathode is capable of long life though occasional premature and poorly understood failures do occur. Life tests have shown lifetimes of several thousand hours without failure.
The electron gun contains a hairpin filament supporting a (100) ‐aligned needle cathode. The thermionic emission from the hairpin and needle shank is suppressed by a grid disk surrounding the needle shank. It has little effect on the electric field at the tip of the cathode. The anode with its aperture is positioned 0.020 in. (0.5 mm) from the tip. The anode is followed by a defining aperture at the anode potential.
The gun geometry provides very little electrostatic‐lens effect to minimize spherical aberration. Imaging is accomplished with two magnetic lenses using collimation of the beam between the lenses to further reduce the spherical aberration. The design of the dual‐lens sytem allows a large clearance between the second lens and the target in order to improve deflection capability and reduce the magnetic field in the vicinity of the target. The action of the first lens was improved by decreasing its focal length such that the electric field of the gun and the magnetic field of the lens became overlapping. The computer analysis of the optics for combined fields was done by A.B. El‐Kareh at the University of Houston. Two types of cathodes have been used. A great deal of experience has been obtained with a zirconiated tungsten cathode using the usual zirconium‐on‐ tungsten cathode suitably supplied with an oxygen interface. A dispensing Zr source on the shank of the needle delivers Zr to the tip by surface diffusion. A lesser amount (but encouraging experience) has been accumulated with a built‐up (100) ‐tungsten cathode using a build‐up procedure developed by L. Swanson of the Oregon Graduate Center. Both cathodes can be operated at temperatures of about 1800 K and a beam current of 0.5 μA in a focused spot of less than 1000 Å diameter has been obtained from both types.
If the built‐up cathode is used, the spot size will be about 350 Å, while that of the zirconiated one with 0.6‐μm radius will be about 950 Å, even though the same electron optics are used. This results from the much smaller source size for the built‐up case. Analysis to be published by El‐Kareh and Moravan shows that both cathodes have much larger emission‐energy spread when operated with an electric field between 2×107 and 4×107 V/cm. This is not a problem, however, at the usual operating field of 1×107 V/cm for the zirconiated cathode and about 6×107 V/cm for the built‐up cathode.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams

New imaging and deflection concept for probe‐forming microfabrication systems

H. C. Pfeiffer

J. Vac. Sci. Technol. 12, 1170 (1975); http://dx.doi.org/10.1116/1.568485 (4 pages) | Cited 11 times

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A projection lens with an integrated deflection yoke has been developed as part of a probe‐forming system for microfabrication. A single yoke is located at the center of the polepiece gap for the purpose of minimizing deflection aberrations through compensation. The concept of a linked imaging trace generates a shaped beam at the target plane. The following performance parameters have been experimentally verified: a resolution of 20 000 lines per field, forming a square spot of 1.25×1.25 μm with an edge slope of 0.25 μm, over a field of 5×5 mm, and a spot current of 0.75 μA, which corresponds to a current density of 50 A/cm2.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams
29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators

Automatic stabilization of an electron‐probe forming system

S. Doran, M. Perkins, and W. Stickel

J. Vac. Sci. Technol. 12, 1174 (1975); http://dx.doi.org/10.1116/1.568486 (3 pages)

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Our electron‐probe forming system for pattern generation is based on the concept of projecting a demagnified image of a physical object on a target. A complex, automatic probe stabilization method was developed, which does not interfere with system operation. The stabilization system consists of five closed‐loop control circuits, activated during beam‐off periods and a dynamic, correction‐function generator to compensate for deflection astigmatism and field curvature. Probe current is stabilized within 5%; resolution is well within the depth‐of‐focus range over the lifetime of a cathode. The stabilization can be continuously operated automatically over many cathode life spans by supplementing the circuitry and by adding control software.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams
29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators

Some aspects of high‐current relativistic electron‐beam generation

D. W. Forster, M. J. Goodman, and H. G. Herbert

J. Vac. Sci. Technol. 12, 1177 (1975); http://dx.doi.org/10.1116/1.568487 (6 pages) | Cited 1 time

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Diode characteristics in two electron‐beam generators, IT and ACE, are examined, with particular reference to the role of prepulse conditions. The advantages and limitations of field‐enhanced edge emitters are discussed. In both low‐ and high‐current‐density applications, a stable impedance–time history is shown to be associated with a band of prepulse voltage which is a function of both its time variation and driving impedance. Above this band rapid impedance collapse occurs, and below it long current switch‐on times are experienced. This behavior is postulated to be dependent upon cathode plasma formation and growth during prepulse and early main pulse phases. The results of a preliminary investigation into the controlled use of prepulse for high‐current‐density beam production from field‐enhanced edges are examined. The characteristics of hollow cylindrical cathodes operating in pinched mode are shown to depend on prepulse conditions. In particular, the transfer of finite energy (of order tens of millijoules) to the diode during the prepulse phase is shown to be desirable for rapid establishment of the required diode impedance in the main pulse phase.
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29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
41.75.Fr Electron and positron beams

OWL II pulsed‐electron‐beam generator

G. B. Frazier

J. Vac. Sci. Technol. 12, 1183 (1975); http://dx.doi.org/10.1116/1.568488 (5 pages) | Cited 8 times

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OWL is a water‐dielectric line‐type pulse generator capable of producing ∠100‐nsec electron beams with total energies of as much as 150 kJ. In its present form, OWL II consists of an oil‐immersed, 1/3‐MJ Marx generator charging a 3.9‐Ω coaxial pulse‐forming line which is series switched into either a two‐ or three‐stage impedance transformer. The output impedance is 1.9 or 1.1 Ω, depending upon which transformer is used, and nominal beam outputs in the two cases are 1.3 MV at 0.8 MA and 0.9 MV at 1.2 MA, respectively. The pulse width can be selected at either 60 or 120 nsec (FWHM of power) by interchanging two available pulse lines. Shot‐to‐shot reproducibility in output of ±2% with a mean electron energy ∠1.0 MeV is obtained with the 1.9‐Ω final transformer. A triggered multichannel water switch minimizes the risetime of pulses injected into the transformer section.
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29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
41.75.Fr Electron and positron beams

15‐kJ LC generator: Low inductance device for a 100‐GW pulsed electron accelerator

N. W. Harris and H. I. Milde

J. Vac. Sci. Technol. 12, 1188 (1975); http://dx.doi.org/10.1116/1.568489 (3 pages) | Cited 1 time

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The design and construction of a 15‐kJ LC generator is described. This type of generator is used for its low inductance compared with more conventional Marx generators. The generator described consists of 20 capacitors rated at 80 kV, 5 reversing switches, and 1 extra‐high‐voltage transfer switch. The generator was built as a primary store for a high current, high power (300 kA, 100 GW) field‐emission electron‐beam generator.
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29.20.Ba Electrostatic accelerators
29.20.Ej Linear accelerators
84.70.+p High-current and high-voltage technology: power systems; power transmission lines and cables
84.30.Sk Pulse and digital circuits

Generation and extraction of microsecond intense relativistic electron beams

R. Schneider, C. Stallings, and D. Cummings

J. Vac. Sci. Technol. 12, 1191 (1975); http://dx.doi.org/10.1116/1.568490 (3 pages) | Cited 2 times

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The Physics International Pulserad 1140 has been modified so that a pulse length of 1.7 μsec can be obtained with a beam energy of 50 kJ. This modification involves substituting a pulse‐forming network for the conventional Blumlein. This long‐pulse generator has been used to study diode behavior on 1‐μsec time scales. The dependence of impedance on voltage and anode–cathode spacing is discussed here. A semiempirical model has been developed. The diode time history and closure velocity are discussed in terms of this model.
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29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
41.75.Fr Electron and positron beams
84.30.Sk Pulse and digital circuits
82.40.-g Chemical kinetics and reactions: special regimes and techniques

ATRI—A Tesla‐transformer‐type electron‐beam accelerator

I. Boscolo, G. Brautti, M. Leo, A. Luches, and M. R. Perrone

J. Vac. Sci. Technol. 12, 1194 (1975); http://dx.doi.org/10.1116/1.568491 (3 pages) | Cited 2 times

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An electron‐beam transformer accelerator is described. Its high voltage terminal rises up to 1.2 MV with an input voltage of 18 kV. The maximum electron‐beam current is 16 kA; the pulse length is about 20 nsec. Aluminized Mylar anodes and foilless anodes are used. With foilless anodes the repetition rate is at present 3 pulses/sec. Pulse shape details are given and discussed to understand the behavior of the machine and its output characteristics. An improvement program is also presented.
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29.20.Ba Electrostatic accelerators
29.20.Ej Linear accelerators
29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
41.75.Fr Electron and positron beams

Secondary‐emission electron gun for high pressure molecular lasers

D. Pigache and G. Fournier

J. Vac. Sci. Technol. 12, 1197 (1975); http://dx.doi.org/10.1116/1.568492 (3 pages) | Cited 5 times

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A new type of high voltage, large area electron gun is described. Ions are generated in a low pressure ion source, extracted by a grid, and accelerated by a −130‐kV continuously biased electrode. By secondary emission, these ions produce electrons which are accelerated toward the grid. They go through the ion source and an electron window (15×5 cm). Electron‐beam density profiles display a good uniformity. The current density, limited only by the available power for the discharge, reaches presently 1 mA/cm2. The advantages of this gun over others are moderate vacuum requirements and capability for both low current cw and high current pulsed beams with easy control at ground potential and small energy requirement.
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29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
42.60.-v Laser optical systems: design and operation

LAMPF experimental‐area beam current monitors

Paul J. Tallerico

J. Vac. Sci. Technol. 12, 1200 (1975); http://dx.doi.org/10.1116/1.568493 (3 pages)

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This paper summarizes the design and operational performance of a wide‐ range current monitor system used to measure charged‐particle currents in the experimental areas of the Clinton P. Anderson Meson Physics Facility (LAMPF), a proton accelerator. The major features of the system are high sensitivity, wide dynamic range, and the ability to withstand high levels of radiation. The current pulses detected are from 50 μs to 1 ms in duration at repetition rates of from 1 to 120 Hz. The pulse amplitude varies from 1 μA to 17 mA of protons or H ions. Both real‐time and integrated outputs are available, and the minimum detectable currents are 1 μA at the video output and 50 nA at the integrated output. The basic system is comprised of toroids, preamplifiers, signal conditioners, voltage‐to‐frequency converters, and digital accumulators. The entire system is spread out over 1 km of beam pipe. Provision is made for calibration and for sending the outputs to remote users. The system is normally controlled by a small digital computer, which allows the system to be quite flexible in operation. The design features of the toroids and the associated electronics are discussed in detail, with emphasis on the steps taken to reduce noise and make the toroids temperature and radiation resistant.
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29.20.Ba Electrostatic accelerators
29.20.Ej Linear accelerators
29.40.-n Radiation detectors

Abstract: Beam energy transfer and propagation in a fully ionized magnetized plasma

C. Ekdahl, M. Greenspan, J. Sethian, and C. B. Wharton

J. Vac. Sci. Technol. 12, 1203 (1975); http://dx.doi.org/10.1116/1.568494 (1 page)

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The interaction of a relativistic electron beam (300–500 kV, 5–40 kA, ν/2<2) with a fully ionized magnetic mirror‐confined plasma column (1012 cm−3<ne<5×1013 cm−3; 0.01<nb/ne<0.3) has been experimentally investigated. Beam density profiles have been obtained using a small Faraday cup with a thin foil‐covered aperture, and by measuring the intensity of x rays generated in small targets. Spatially resolved current profiles have been measured with small magnetic flux loops. Beam energy has been determined by varying the foil thickness covering the Faraday‐cup aperature and by graded‐foil‐absorber energy analysis of the target x‐ray emission. The energy transfer to the plasma column has been measured with diamagnetic loops, and the ion energy distribution has been determined with a multichannel analyzer.
Results indicate up to 8% transfer of the diode energy to heating of the plasma column with the energy per electron–ion pair increasing linearly with the beam to plasma density ratio nb/ne. Ion energy distribution with high energy tails is observed. Following beam injection, oscillations are observed on the plasma column which propagate with the Alven velocity. 80%–98% current neutralization is observed. From the decay of currents which persist after the passage of the beam, a plasma resistivity can be inferred for the plasma column which is three to four orders of magnitude greater than the Spitzer resistivity calculated for the plasma column.
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52.40.Mj Particle beam interactions in plasmas
52.25.Fi Transport properties

Progress in intense pulsed ion sources

Stanley Humphries

J. Vac. Sci. Technol. 12, 1204 (1975); http://dx.doi.org/10.1116/1.568495 (4 pages) | Cited 5 times

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Progress in the development of intense, pulsed ion sources is described. The major impediment, electron breakdown, can be solved by magnetic insulation of the accelerating gap or reflex geometries. Both magnetic insulation and the reflex triode have been used successfully at Cornell to efficiently generate multikiloampere ion fluxes. Scaling of these devices to the range of parameters attained by pulsed electron machings (MA in the MV range) appears feasible. Such ion beams may have applications in plasma heating, ion ring production, thermonuclear pellet compression, and other areas of physical research.
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29.25.Lg Ion sources: polarized
29.25.Ni Ion sources: positive and negative
41.75.Ak Positive-ion beams
41.75.Cn Negative-ion beams
29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators

Abstract: Intense field‐emission ion source of liquid metals

R. Clampitt, K. L. Aitken, and D. K. Jefferies

J. Vac. Sci. Technol. 12, 1208 (1975); http://dx.doi.org/10.1116/1.568496 (1 page) | Cited 29 times

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Intense ion beams are of interest in fusion research for plasma heating, diagnostics, and target compression and in industry for implantation, microfabrication, etc.
We report the generation of intense beams of metal ions of Li, Cs, Sn, Ga, and Hg by field‐ion emission of molten metal films on solid wire needles. The source is extremely simple and is based on electrohydrodynamic instabilities induced in liquid films under electric stress. In practice, for a point‐source or needle emitter, a tungsten needle protrudes from the surface of the molten metal which, with good wetting, flows as a thin film to the needle apex. Application of a potential difference between the needle anode and an apertured cathode results in an electrohydrodynamic instability in the film which is manifested as a filamentary cusp at the needle apex. The electric field intensity at the cusp is sufficient to produce intense atomic‐ion emission by field ionization. When the protruding length of the needle through the molten metal pool is appropriately adjusted, the tip becomes self‐feeding and continuous ion emission occurs.
Direct currents of 50–700 μA can be readily produced from single needles at modest voltages (3–10 kV). Examination of the liquid cusp in an electron microscope shows that the radius of the emitting zone is ?104 Å, suggesting ion current densities in excess of 104 A/cm2. Source scaling can be achieved with an array of needles. Alternatively, one can use a linear or annular edge over which the molten metal flows as a thin film. In the latter source the ion emitting sites are generated along the edge by the field at a frequency given by λ=8πS/3ϵ0E2, where S is surface tension and E is field strength.
Ion emission is accompanied by light emission from a microscopic spot (10–50 μm) at the anode apex. The anode emission process bears some phenomenological similarities to anode spots and cathode spots in vacuum arcs and to pulsed high‐current pinched plasma jets formed on pointed anodes or from exploding wires. Such plasmas are known to be dynamic linear pinches. What we have produced is a microscopic metal‐vapor plasma ball, and we have found a way of anchoring this to allow continuous operation. We do not know by what mechanism the intense plasma spot forms; almost certainly it is initiated by field ionization, the electrons perhaps being generated by ion collisions with the metal vapor. Heating and evaporation of the anode jet could be by I2R heating or by electrons accelerated across the anode drop between plasma ball and liquid surface.
As a stable plasma ball it is novel and readily lends itself to plasma diagnostics. Also by rapidly discharging a high current at high voltage through the anode it should provide a source of a minute dense plasma more reproducibly than presently attained and an intense pulsed source of ions, light, and x rays.
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29.25.Lg Ion sources: polarized
29.25.Ni Ion sources: positive and negative
41.75.Ak Positive-ion beams
41.75.Cn Negative-ion beams
79.70.+q Field emission, ionization, evaporation, and desorption

Study of a field‐ionization source for microprobe applications

J. H. Orloff and L. W. Swanson

J. Vac. Sci. Technol. 12, 1209 (1975); http://dx.doi.org/10.1116/1.568497 (5 pages) | Cited 17 times

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Operating parameters for a field‐ionization source have been measured. Sensitivities of 5×10−5 A sr−1 Torr−1 were found at 77 K. Angular distributions are uniform near ϑ=0° and show the beam to be confined to ±20°. The beam signal‐to‐noise ratio was found to increase with increasing current. Calculations based on parameters of lenses in use indicate a resolution of 0.1 μm at ≳10−10 A is possible.
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29.25.Lg Ion sources: polarized
29.25.Ni Ion sources: positive and negative
79.70.+q Field emission, ionization, evaporation, and desorption
41.75.Ak Positive-ion beams
41.75.Cn Negative-ion beams

Two‐dimensional ion effects in relativistic diodes

J. W. Poukey

J. Vac. Sci. Technol. 12, 1214 (1975); http://dx.doi.org/10.1116/1.568498 (4 pages) | Cited 17 times

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In relativistic diodes, ions are emitted from the anode plasma. The effects and properties of these ions are studied via a two‐dimensional particle‐simulation code. The space charge of these ions enhances the electron emission, and this additional current (including that of the ions themselves) aids in obtaining superpinched electron beams for use in pellet fusion studies.
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28.52.-s Fusion reactors
52.40.Mj Particle beam interactions in plasmas
52.65.-y Plasma simulation

A contribution to explain the deep penetration of high‐power‐density electron beams in metals

W. Schebesta

J. Vac. Sci. Technol. 12, 1218 (1975); http://dx.doi.org/10.1116/1.568499 (3 pages)

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Contrary to the widespread opinion that an electron beam evaporates the material when used as a tool, observations are described which can be explained more satisfactorily with an explosion mechanism. When the electron beam penetrates deeply into the material, regular oscillations of the target current are observed. The main features of these oscillations for various materials are described. These oscillations are explained by intermittent thermionic emissivity and explosions of the energy transfer zone.
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79.20.Kz Other electron-impact emission phenomena
61.85.+p Channeling phenomena (blocking, energy loss, etc.)
29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators

Abstract: Temperature profiles of targets bombarded by electron beams

A. B. El‐Kareh and K. Y. Y. Moravan

J. Vac. Sci. Technol. 12, 1221 (1975); http://dx.doi.org/10.1116/1.568500 (1 page) | Cited 1 time

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A detailed theoretical calculation is presented of the relationship between the spot size and temperature as a function of the physical properties of a target material when it is bombarded by an electron beam. As a result of this analysis, it is possible to determine the desired characteristics of materials which are suitable for application in mass‐storage devices.
The thermal problem can be analyzed by solving the appropriate radial heat‐flow equation. The electron beam heating of the target can be determined within certain limitations by assuming that the heat is generated uniformly in a spot of hemispherical shape whose radius is given by the effective range of electron penetration. This range is determined by making use of the universal curve of the normalized Bohr–Bethe range obtained by Everhart and Hoff.
From the above calculation, the properties of suitable targets can be obtained. It is found that to have a small spot, a high mass density of the target is desirable. The requirement that the equilibrium temperature to be greater than the boiling temperature of the target sets an upper limit for the conductivity of the target. In order for the rise time (the time needed for temperature at the center of the spot to reach a significant portion of the equilibrium temperature value) to be of the same order as the machining time, a lower limit for conductivity and the inter‐relationship between heat capacity, conductivity, and mass density can be obtained. A set of curves are given to show the space and time dependence of the temperature of the spot being machined for different beam powers. It can be seen that both higher temperature and better resolution can be obtained for electron‐beam powers between 2.5 and 10 keV than for above 10 keV.
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79.20.Kz Other electron-impact emission phenomena
29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators

Progress in computer simulation of electron guns for machining

A. Schuler, W. Lorenz, and M. Kneidinger

J. Vac. Sci. Technol. 12, 1222 (1975); http://dx.doi.org/10.1116/1.568501 (5 pages)

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In order to increase the power density in the spot of an electron beam by optimum designing of electrodes and lenses in the electron‐optical system for electron‐beam machining, a digital computer program was written. Parts of the various numerical techniques in this program, carried out on a CDC CYBER 70 Computer, are described: (1) The potential distribution was calculated with the help of the ’’extrapolated‐line Liebmann method,’’ which, compared with the usual SOR method, shortened the calculation time down to a fifth and proved to be more accurate. (2) In order to examine the influence of insulators a method was developed which, with the aid of the polarization charge on the dielectric surface, was used to calculate the resulting potential distribution. (3) To calculate the electron trajectories in an electric field, a semianalytical method was devised, which, compared to the usual method (evaluating the terms in the Lorentz equation with the aid of Taylor series) produces a higher level of accuracy. (4) The calculation of the beam current density, based on the varying distances of the electron trajectories along the beam, was extended to nonlaminar beams, which made it possible to evaluate the radial current density distribution even in a spot of some micrometers diameter. Tested simple cases showed that errors are below 1%.
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41.75.Fr Electron and positron beams
06.60.Vz Workshop procedures (welding, machining, lubrication, bearings, etc.)

Abstract: Analysis of a temperature‐field electron gun

A. B. El‐Kareh

J. Vac. Sci. Technol. 12, 1227 (1975); http://dx.doi.org/10.1116/1.568502 (1 page)

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The temperature‐field (TF) gun described by J. E. Wolfe and L. Swanson was analyzed using a high‐speed digital computer. The field is approximately 107 V/cm and the temperature 1800 K. From scanning electron microscope micrographs of needles used in TF guns (where tungsten needles are chemically etched), it was found that the profile is very close to an ellipsoid. The potential distribution in the gun region and around the needle was obtained by a relaxation technique. Due to the high field strength in the vicinity of the cathode, the mesh size had to be extremely small, of the order of 1 Å. In order to decrease the storage and computer time requirements, the entire gun was initially analyzed with a mesh size of 4 μm. This size was systematically cut by factors of 2 together with the area of the gun being analyzed. The potential distribution for each region and mesh size was stored for the trajectory calculation. Starting from the cathode, or needle tip, a family of trajectories with initial conditions consisting of various slopes, heights, and thermal velocities were calculated until they emerged from the gun or reached a field‐free region beyond the anode. From their heights and slopes in that region, the disk of minimum confusion was calculated by projecting back all the trajectories and searching for the narrowest constriction. It was found that, for an anode voltage of 5000 V and a temperature of 1800 K, the disk of minimum confusion is approximately 120 Å in diameter.
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29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
41.75.Fr Electron and positron beams

Comparative study of the zirconiated and built‐up W thermal‐field cathode

L. W. Swanson

J. Vac. Sci. Technol. 12, 1228 (1975); http://dx.doi.org/10.1116/1.568503 (6 pages) | Cited 11 times

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Angular distribution, total energy distribution, and noise measurements have been carried out on both a zirconium coated and built‐up W(100) field cathode operating at high temperature (1400–1800 K). The effect of residual gas on the emission characteristics and emitter life was also measured. The results show that high brightness (∠1010 A cm−2 sr−1) operation with <10% noise levels and <1.5‐eV energy spread in a 0.079‐msr‐ beam solid angle can be achieved. Emitter longevity in excess of 1000 h in 10 nTorr (1.3 ‐ 10−7 Pa)gas pressure has been observed.
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79.70.+q Field emission, ionization, evaporation, and desorption
41.75.Fr Electron and positron beams
72.70.+m Noise processes and phenomena

Abstract: Electron‐beam‐pattern‐generator applications in the wider field of conventional semiconductor device technology

P. A. Charman

J. Vac. Sci. Technol. 12, 1234 (1975); http://dx.doi.org/10.1116/1.568504 (1 page)

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Most electron‐beam microfabrication systems now in existence have been built ’in house’ for the production of special masks or devices on a relatively small scale. The fabrication of a variety of submicron structures by such systems is a well documented subject.
However, the bulk of present day and foreseeable‐future output from the semiconductor industry is based on devices with linewidths in excess of 2 μm. This is a function of the limitations of established processing techniques as much as the limitations of photolithography. It is proposed that a versatile electron‐beam system can offer significant overall advantages in many applications in this field.
A prime application is the saving of time in the proof of new complex circuit designs by using an electron‐beam system as a 1× pattern generator so that the first set of masks for a new design can be made directly from a CAD system tape in one day. Such masks would be free from the repetitive defects and misalignments exhibited by the present optical‐pattern‐generator–image‐repeater combination. It would be possible to include design variations on each layer without the intolerable time penalty incurred by making and changing optical reticles. Design optimization should therefore be possible with the minimum of mask remaking.
In some circumstances, direct exposure of a single wafer could provide even faster availability of proving circuits, while eliminating the yield loss inherent in mask‐alignment problems.
A specification for an electron‐beam system capable of performing the above functions should include a minimum practical linewidth of 2 μm, a maximum chip area of 10×10 mm and a maximum mask or wafer size of 100×100 mm. The system must be capable of exposing 25% of the maximum‐size workpiece in under two hours. There is a requirement for automatic electronic registration on a ’per chip’ basis for both mask and wafer exposure, and for laser‐interferometer stage monitoring to permit assembly of subfields if chip size and resolution requirements go beyond the capabilities of the basic system. The maximum beam current should be 2×10−7A at 15 keV, stable to ±2% over 1 h; electron energies should be 10, 15, 20, and 25 keV. The total image distortion (including misalignment of beam to target) should not exceed ±0.2 μm within each electronically scanned subfield of 2.5×2.5 mm. The system must accept standard inputs as presently used for optical pattern generators.
Such a system could completely replace the present optical‐pattern‐generator–image‐repeater combination and would satisfy the growing demand for near‐perfect masks. It would also be able to directly expose devices whose dimensions and complexity produce alignment problems which even perfect masks could not resolve. Present device processing can achieve far more in terms of better yield and throughput by improving dimensional control on a layer‐to‐layer basis than it can by higher resolution lithography. The potential for electron‐beam pattern generators to outperform existing optical image repeaters, contact printers, and projection printers in this respect appears to be the key to their wider use in the semiconductor industry.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams

Electron‐beam lithography using vector‐scan techniques

A. J. Speth, A. D. Wilson, A. Kern, and T. H. P. Chang

J. Vac. Sci. Technol. 12, 1235 (1975); http://dx.doi.org/10.1116/1.568505 (5 pages) | Cited 3 times

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A computer‐controlled electron‐beam microfabrication system has been developed for evaluation of micron and submicron lithographic technologies. Direct large‐field‐device exposures of complex patterns have been processed for FET and bubble memory fabrication. Experimental exposures have also been made to allow mask fabrication for alternative exposure apparatus. The system exposes the electron‐sensitive resist by sequentially filling in pattern elements (cells), whose geometry and size are determined by an off‐line pattern data processor. Abutting line scans, using a round electron probe, are used to expose each cell. The system normally exposes fields up to 4 mm square. Deflection resolution is 14 bits per axis. Exposure rate, pattern registration, pattern field adjustments (size, position offset, rotation, and orthogonality), and workstage position are among the functions which have been automated.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
85.30.Tv Field effect devices
07.05.Wr Computer interfaces
41.75.Fr Electron and positron beams

Experimental scanning electron‐beam automatic registration system

A. D. Wilson, T. H. P. Chang, and A. Kern

J. Vac. Sci. Technol. 12, 1240 (1975); http://dx.doi.org/10.1116/1.568506 (6 pages) | Cited 7 times

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An experimental automatic registration system is discussed that is capable of precisely overlaying two or more levels of a microcircuit pattern written by an electron‐beam lithographic machine. Because positional information of the registration marks arrives at the detector in the form of random discrete quanta, it is subject to the statistical fluctuations inherent in all such systems. Achievement of a signal‐to‐noise ratio adequate for precise registrations with inherently noisy backscattered electrons and without overexposure of the resist layers covering the registration mark is accomplished using digital signal enhancement techniques. Manual and computer methods have been developed to correct field size, shift, rotation, and orthogonality. Correlation between manual and automatic registrations and the pattern are excellent because the same basic deflection and electronics systems are used for all three modes of operation. The necessary software to control the registration subsystems and to perform registration computations and edge detection have also been developed. Registration overlays have been made automatically with absolute errors on the order to 100 ppm. For a 2‐mm chip, this is a level‐to‐level error of about ±0.1 μm. Several samples of typical complex microcircuit patterns registered with this experimental automatic system are shown.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams

A pattern generation technique for serial electron‐beam microfabrication systems

F. S. Ozdemir, C. R. Buckey, and E. D. Wolf

J. Vac. Sci. Technol. 12, 1246 (1975); http://dx.doi.org/10.1116/1.568507 (5 pages)

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A hybrid electron‐beam pattern generation technique is described which utilizes both digital point‐by‐point high resolution pattern definition and an analog ramp low resolution pattern fill‐in. The analog ramp endpoints are set by the digital‐to‐analog converters and are thereby self‐registered to the digital point‐by‐point exposure. This dual approach to pattern exposure allows tradeoffs to be made in the performance required of the individual components which make up the pattern generator. Examples of these tradeoffs are discussed. An overall system throughput model was developed and applied to a specific system based on this hybrid pattern generator. The results of applying this model to the 0.1–1.0‐μm‐linewidth range shows that throughput is strongly influenced by line broadening effects such as electron scattering and processing in the 0.4–1.0‐μm‐line resolution range and that alignment times (mechanical stage and electron beam) become dominant in the 0.4–1.0‐μm range.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams
79.20.Kz Other electron-impact emission phenomena

Abstract: Electromask generator

J. P. Beasley and D. G. Squire

J. Vac. Sci. Technol. 12, 1251 (1975); http://dx.doi.org/10.1116/1.568508 (1 page)

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An electron‐beam pattern generator has been made for mask fabrication, either for conventional photolithography or more specifically for making electromasks for use in an image projection system. The maskmaker draws the pattern required at the final size in electron‐sensitive resist which in turn defines the pattern in an opaque metal film on a transparent substrate. A 50‐mm ‐square mask covered with detail down to at least 1 μm can be made in less than three hours. To achieve this speed of working two stages of beam deflection are used together with mechanical movement of the substrate. The high‐speed deflection system runs at a 10‐MHz stepping rate over a maximum amplitude of 32 μm. The slow‐speed system covers an area of 2×2 mm.
An array of markers predefined over the substrate is used to obtain a pattern accuracy of ±1/8 μm relative to these markers. They are also used to check and, if necessary, correct the beam focus after each mechanical movement of the table. The pattern drawing, positioning, and beam focusing are entirely automatic.
An integrated‐circuit mask‐generation program is used on a larger computer to prepare the data for the patterns to be drawn. Magnetic tape is used to transfer this data to the maskmaker’s small computer.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams

Abstract: Controlled‐energy micropositioning system for high‐vacuum applications

M. R. Wojtaszek, J. K. Hassan, and D. F. Haire

J. Vac. Sci. Technol. 12, 1251 (1975); http://dx.doi.org/10.1116/1.568509 (1 page)

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The operation of a high‐performance positioning system within a high‐vacuum environment poses several restraints on configuration and materials selection. To overcome these physical design limitations and reduce their effect on the dynamic performance of the positioning system, a technique for achieving optimum energy usage during stepping has been developed and evaluated. Principles used in developing this technique are reviewed; their application is illustrated through the use of simulation techniques and actual test results. System design requirements, control system configuration, and simulation will be discussed. Dynamic performance and accuracy objectives are emphasized.
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07.30.Kf Vacuum chambers, auxiliary apparatus, and materials
06.60.Sx Positioning and alignment; manipulating, remote handling

Control system design and alignment methods for electron lithography

D. S. Alles, F. R. Ashley, A. M. Johnson, and R. L. Townsend

J. Vac. Sci. Technol. 12, 1252 (1975); http://dx.doi.org/10.1116/1.568510 (5 pages) | Cited 2 times

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The electron‐beam exposure system (EBES) was designed to economically expose integrated circuit masks on a production basis and to directly pattern semiconductor substrates for special applications where a limited number of devices are required. The machine was designed to assure absolute pattern accuracy over the entire substrate so that masks made by EBES will be interchangable with those made by our optical mask shop or those made by later electron‐beam pattern generators. This has been achieved by a combination of control system design and by automated periodic system alignment. The control system design utilizes a laser interferometer to determine precise table position and a feedback system that continuously corrects the writing‐beam location for errors in table location. This combination, coupled with a small‐angle electron‐beam deflection system using an ultrastable sawtooth‐scan generator to achieve repeatable beam positioning over a small writing area, allows exposure rates of 107 addresses per second with submicron absolute accuracies over a 10×10‐cm area. A series of automated measurements have been implemented in order to maintain this accuracy for extended periods. Every five minutes beam‐positioning errors resulting from external magnetic fields, temperature variations, and amplifier drifts are measured by using the electron column as a scanning electron microscope to locate a registration mark permanently affixed to the table. Several times a day, the deflection system is automatically adjusted under computer control to assure that the electron‐beam deflection axes agree precisely with the interferometer‐controlled table motion in both magnitude and direction. Periodically, a set of special test patterns are written by EBES and then, using EBES as a computer‐controlled coordinate measuring machine, these patterns are measured and analyzed to provide an accurate assessment of the machine’s true writing performance. This alerts the mask shop to potential problems and allows service personnel to make the necessary corrections before the final product is materially affected.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams
29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators

Electron‐beam fabrication of chromium master masks

J. P. Ballantyne

J. Vac. Sci. Technol. 12, 1257 (1975); http://dx.doi.org/10.1116/1.568511 (4 pages) | Cited 2 times

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Conventional photolithographic methods of mask manufacture in the semiconductor industry have limitations which can be overcome using electron lithography. This paper describes application of the electron‐beam exposure system (EBES) to the fabrication of chromium master masks using the negative electron resist poly(glycidyl methacrylate‐co‐ethyl acrylate). Lithographic characterization methods developed specifically for this application include the variation of feature size and develped resist thickness with exposure and have led to the choice of correct operating conditions for EBES. Writing time for a typical 2.5‐in. (6.35‐cm) mask is 30–60 min, and processing time is about 70 min (excluding inspection and handling). Linewidth control is better than ±0.5 μm and chip yields typically exceed 90% per mask level for LSI circuits. Masks with chip sizes up to 20×16 mm have been processed. One‐micrometer feature sizes are obtained routinely.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams

Abstract: Pattern generation on wafers using the electron‐beam exposure system (EBES)

R. C. Henderson, A. M. Voshchenkov, and G. E. Mahoney

J. Vac. Sci. Technol. 12, 1261 (1975); http://dx.doi.org/10.1116/1.568512 (1 page)

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Using the electron‐beam exposure system (EBES) for direct pattern generation on wafers offers the means to make circuits with feature dimensions of only a few micrometers and alignment tolerances less than 1 μm. For such a program to be successful, techniques had to be developed to (a) rapidly register the pattern, (b) minimize the writing time, and (c) pattern the various thin films used in circuit fabrication.
For pattern registration, EBES need only determine the positions of three nonlinear fiducial marks which form a triangle spanning most of the wafer area. The position data are used to calculate the translation, rotation, skew, and magnification required to get the best fit of the old pattern to the new. The corrections are applied to the electron‐beam writing operation. It takes less than two minutes to register an entire 2‐in. (5.08‐cm) wafer to within a ±1/2‐μm accuracy.
The writing time is usually less than 20 min to expose all the chips fully covering a 2‐in. (5.08‐cm) Si wafer, even when there are three or four different types of circuit on the wafer. This can be achieved by laying out the chips to specifically match the EBES writing characteristics.
The resist used has been poly (glycidyl methacrylate‐co‐ethyl acrylate), a sensitive negative electron resist. Techniques were devised to etch patterns on many different substrates following resist development.
For pattern generation on Si wafers, the substrates included thin films of SiO2 (thermally grown as well as CVD), Si3N4, W, polysilicon, Al, and Ti–Pd–Au (see Table I). Subsequently, MOS circuits were made with combinations of the above techniques. These circuits2 include 1024‐bit RAM’s, some with 5.5‐μm gates, 3.0‐μm contact holes, and 4.5‐μm interconnecting metallization. Also, inverters, as well as discrete IGFET’s with gate lengths varying from 2 to 12 μm, were made.
EBES has also been used to delineate the thin film patterns required for GaAs MES FET fabrication (see Table II). Some devices have up to fourteen 2.5‐μm gates with 2.5‐μm gate‐to‐source spacings while others have single 2.0×500‐μm gates with 2.0‐μm spacings. These devices require alignment better than ±0.25 μm and metal conductors with thickness‐to‐width ratios as high as 1/2. Single gate MES FET’s made in this way have values of transconductance of up to 25 mmhos.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
79.20.Kz Other electron-impact emission phenomena
41.75.Fr Electron and positron beams

Application of moiré techniques in scanning‐electron‐beam lithography and microscopy

Henry I. Smith, S. R. Chinn, and P. D. DeGraff

J. Vac. Sci. Technol. 12, 1262 (1975); http://dx.doi.org/10.1116/1.568513 (4 pages) | Cited 5 times

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When a grating is viewed by scanning electron microscopy, a moiré pattern is observed. Applications of the moiré phenomenon in scanning‐electron‐beam lithography and microscopy are discussed, including adjustment of the spatial period and angle of a scan raster, analysis of distortion in a scan raster, analysis of stray‐field beam deflection and measurement errors, and registration of a scan field relative to coded patterns on a substrate.
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07.78.+s Electron, positron, and ion microscopes; electron diffractometers
41.75.Fr Electron and positron beams
85.40.Bh Computer-aided design of microcircuits; layout and modeling

Composition and detection of alignment marks for electron‐beam lithography

E. D. Wolf, P. J. Coane, and F. S. Ozdemir

J. Vac. Sci. Technol. 12, 1266 (1975); http://dx.doi.org/10.1116/1.568514 (5 pages) | Cited 6 times

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High energy backscattered electron signals have been measured from 1‐, 3‐, and 10‐μm‐wide gold alignment marks on silicon and gallium arsenide substrates as a function of electron‐beam energy (5–30 keV) and gold film thicknesses (650–10 000 Å) using an annular silicon‐diode detector. Thin films of both silicon dioxide (3500 Å) and polymethyl methacrylate (5200 Å) on gold alignment marks (2600 Å) on silicon reduced the original signal contrast at 30‐keV incident‐beam energy by only 16% (10% and 6%, respectively) and degraded the original edge acuity by only about a factor of two. Signal contrast maxima for gold on silicon and gold on gallium arsenide were found to be 1.64 and 0.86, respectively, while silicon and silicon dioxide steps (∠4000 Å) produced no more than 0.08 and 0.04 contrast, respectively. The gold on silicon results are presented with the full realization of the general processing incompatibility of gold on silicon devices and circuits at high temperatures. These results are applicable to other high‐atomic‐number materials which can be optimized for a particular electron‐beam lithography process. The advantage of efficient high‐energy backscattered electron detection and high‐atomic‐number alignment marks to produce high‐contrast video signals which are not significantly degraded by the addition of low‐atomic‐number thin films (e.g., SiO2, resists) will become increasingly important when very accurate alignment is required (±0.05 μm).
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams
29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
79.20.Kz Other electron-impact emission phenomena

Proximity effect in electron‐beam lithography

T. H. P. Chang

J. Vac. Sci. Technol. 12, 1271 (1975); http://dx.doi.org/10.1116/1.568515 (5 pages) | Cited 85 times

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A simple technique for the computation of the proximity effect in electron‐beam lithography is presented. The calculations give results of the exposure intensity received at any given point in a pattern area using a reciprocity principle. Good agreement between the computed results and experimental data was achieved.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams
29.25.-t Particle sources and targets
29.27.-a Beams in particle accelerators
79.20.Kz Other electron-impact emission phenomena

Recent developments in electron‐resist evaluation techniques

M. Hatzakis

J. Vac. Sci. Technol. 12, 1276 (1975); http://dx.doi.org/10.1116/1.568516 (4 pages) | Cited 2 times

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A simple procedure for evaluating the performance of any positive electron resist is presented. SEM examination of the developed resist edge profile after electron‐beam exposure and development gives simultaneous information on resist sensitivity and resolution for a given resist thickness. This method gives a unique exposure charge‐density point for optimum resolution for a given resist system independent of developer strength.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams
79.20.Kz Other electron-impact emission phenomena

Molecular parameters and lithographic performance of poly(glycidyl methacrylate‐co‐ethyl acrylate): A negative electron resist

L. F. Thompson, J. P. Ballantyne, and E. D. Feit

J. Vac. Sci. Technol. 12, 1280 (1975); http://dx.doi.org/10.1116/1.568517 (4 pages) | Cited 4 times

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To facilitate the production of a polymeric electron resist of consistent quality we must know how molecular parameters are related to lithographic performance. Previous work has indicated that for negative resists in general, sensitivity and contrast increase with increasing molecular weight and decreasing polydispersivity, respectively. We describe experiments on eight batches of a particular resist, poly(glycidyl methacrylate‐co‐ethyl acrylate) [P(GMA‐co‐EA)], which compare lithographic performance, in terms of sensitivity, contrast, and edge sharpness, with molecular weight (Mw), molecular content (%GMA), and polydispersivity (Mw/Mn). The earlier conclusions are borne out. To achieve a sensitivity of 4×10−7 C cm−2 at 10 kV and a contrast of about 1.0 (the latter being needed for lithography for chromium photomask production), the required values for this resist of Mw, %GMA, and Mw/Mn are, respectively, ?1.6×105, 70±2, and ?3.0.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams
81.05.Lg Polymers and plastics; rubber; synthetic and natural fibers; organometallic and organic materials
79.20.Kz Other electron-impact emission phenomena

Electron scattering and line profiles in negative electron resists

R. D. Heidenreich, J. P. Ballantyne, and L. F. Thompson

J. Vac. Sci. Technol. 12, 1284 (1975); http://dx.doi.org/10.1116/1.568518 (5 pages) | Cited 4 times

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Starting with a depth‐dose theory of electron energy dissipation in negative electron resists and a quasimonoenergetic Gaussian scattering theory, we derive theoretical expressions for single‐line profiles using the exposure parameters of the Bell Laboratories electron‐beam exposure system (EBES). These profiles are calculated by convoluting the Gaussian scattering distribution with the experimentally determined relationship between resist thickness remaining after development and input electron dose. Calculated profiles for the negative electron resist P(GMA‐co‐EA) agree well with experimental results for the range of feature sizes exposed on EBES. Since features on EBES are built up by multiple passes, the theory is extended to line profiles separated by the address structure of EBES. The calculated resist profiles are in reasonably good agreement with experimental results. The observed profile heights are somewhat greater than predicted by theory since the developed gel is not perfectly rigid and gel interaction takes place between neighboring profiles. The results show the importance of good gel rigidity and high contrast for negative electron resists used in high resolution applications. The range of validity of the trends predicted by the quasimonoenergetic theory for increasing film thickness and operating voltage are extended using a Monte Carlo approach which includes the effects of energy loss. The calculated trends have led to the choice of optimum exposure conditions for EBES.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams
79.20.Kz Other electron-impact emission phenomena

Cross‐section profiles of single‐scan negative electron‐resist lines

L. H. Lin

J. Vac. Sci. Technol. 12, 1289 (1975); http://dx.doi.org/10.1116/1.568519 (5 pages) | Cited 3 times

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The profile of a negative electron‐resist line resulting from a single‐scan exposure to an electron beam can provide much fundamental information in high‐resolution lithography. A simple experimental method for determining this profile is presented here. The method is based on the measurements of the beam radius in the resist film and the contrast characteristics of the resist. The resist profile is calculated from the incident beam radius and current, the beam radius at the resist–substrate interface, and the resist contrast and exposure threshold. The calculated results are then compared with measurements taken from cross‐section scanning electron micrographs of actual resist lines. Good agreement has been obtained in spite of the simplicity of the described method and approximations involved.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams
79.20.Kz Other electron-impact emission phenomena

Poly(butene‐1 sulfone) —A highly sensitive positive resist

M. J. Bowden, L. F. Thompson, and J. P. Ballantyne

J. Vac. Sci. Technol. 12, 1294 (1975); http://dx.doi.org/10.1116/1.568520 (3 pages) | Cited 6 times

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The positive electron resist poly(butene‐1 sulfone) (PBS) has been reported previously. As with other electron resists, sensitivity has been shown to be dependent on a number of processing parameters such as accelerating voltage, developer, developer solvent, and polymer characteristics (namely, molecular weight, molecular weight distribution, etc.). Previous reports have involved resist samples and conditions resulting in sensitivities within the range of 4–6×10−6 C/cm2 at 10 kV. For certain uses, for example, on the Bell Laboratories electron beam exposure system (EBES), a sensitivity of better than 1×10−6 C/cm2 at 10 kV is desired for efficient operation. Recent studies involving samples of varying molecular parameters verify feasibility of sensitivities of 7–8×10−7 C/cm2 at 10 kV for carefully controlled molecular weight and molecular weight distribution. As expected, processing of PBS at this sensitivity requires careful attention to polymer dissolution mechanisms. An ideal developing system should dissolve the irradiated region while hardly swelling the unirradiated region. This requires a developing solvent to be kinetically poor but thermodynamically good. Swelling and loss of resolution can occur when these conditions are not fulfilled.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
61.80.Fe Electron and positron radiation effects
81.05.Lg Polymers and plastics; rubber; synthetic and natural fibers; organometallic and organic materials

Fabrication of a miniature 8K‐bit memory chip using electron‐beam exposure

H. N. Yu, R. H. Dennard, T. H. P. Chang, C. M. Osburn, V. Dilonardo, and H. E. Luhn

J. Vac. Sci. Technol. 12, 1297 (1975); http://dx.doi.org/10.1116/1.568521 (4 pages) | Cited 7 times

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A fully‐ion‐implanted miniature 8192‐bit random‐access memory chip has been fabricated using electron‐beam lithography with minimum linewidth between 1 and 1.5 μm and advanced Si FET technology. Device structure, processing steps, mask transfer, and reactive ion etching processes capable of fabricating device structures in the micrometer and submicrometer dimensions are described. With a minimum linewidth of 1.25 μm, the memory chip occupies an area of 1.1×1.6 mm with an array density of 5 million bits/in.2 (0.8 million bits/cm2). A typical readout access time of 90 ns was measured on a functional chip.
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85.30.Tv Field effect devices
85.40.-e Microelectronics: LSI, VLSI, ULSI; integrated circuit fabrication technology
61.72.U- Doping and impurity implantation
41.75.Fr Electron and positron beams

Electron‐beam‐delineated X‐band silicon transistor

James B. Kruger, You‐Sun Wu, and Han‐Tzong Yuan

J. Vac. Sci. Technol. 12, 1301 (1975); http://dx.doi.org/10.1116/1.568522 (3 pages) | Cited 1 time

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An X‐band silicon power transistor has been used to develop and demonstrate electron‐beam lithography in a multilevel device with submicron geometries. The importance of an automatic registration system capable of submicron precision will be discussed. The difficulties of processing submicron geometries once they have been defined in resist and the means of addressing these problems will be reported. Dry etch processes such as plasma etch and ion milling have definite advantages. The benefits in resolution and registration of direct slice writing with an electron beam are, of course, offset in some degree by the reduced throughput caused by serial patterning. Therefore, a hybrid approach was taken, using the e beam only for the three levels in which its superior resolution and registration are critical. Photomasks are used for three noncritical levels. Comparison with a completely photolithography‐defined device will be made to show the advantages in performance and yield of the e‐beam device. A single‐cell e‐beam‐generated transistor with 1/2‐μm emitters has demonstrated a significant advancement in the state of the art: 230 mW cw amplifier output power with 6.7 dB gain and 25% collector efficiency (20% power added efficiency) at 10 GHz.
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85.30.Pq Bipolar transistors
85.40.Xx Hybrid microelectronics; thick films
41.75.Fr Electron and positron beams
79.20.Kz Other electron-impact emission phenomena

Abstract: Fabrication of microelectronic devices with electron‐beam lithography

C. H. Ting, M. Hatzakis, and R. A. Leone

J. Vac. Sci. Technol. 12, 1304 (1975); http://dx.doi.org/10.1116/1.568523 (1 page)

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A variety of semiconductor devices have been fabricated by scanning‐electron‐beam lithography to demonstrate not only high resolution lithography but also to show that adequate associated processes exist for making properly functioning devices. The resist used was poly‐methyl‐methacoylate (PMMA) (DuPont, Elvacite 2010) developed in methyl iso‐butyl ketone. The devices include npn bipolar transistors with As emitters,1 n‐ and p‐channel MOS FET’s with gate lengths from 1.25 to 7.5 μm,2–4 n‐channel ring oscillators with 1‐μm gate lengths,5 CMOS ring oscillators with minimum linewidths of 1.25 μm, and a three‐phase CCD with 3‐μm‐long electrodes and 1‐μm gaps. By combining state of the art electron optics6,7 with newly developed electron resists, scanning‐electron‐beam lithography could be an attractive technique for making devices and circuits.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams

Monte Carlo simulation of spatially distributed beams in electron‐beam lithography

D. F. Kyser and N. S. Viswanathan

J. Vac. Sci. Technol. 12, 1305 (1975); http://dx.doi.org/10.1116/1.568524 (4 pages) | Cited 23 times

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The spatial distribution of energy deposited in a thin polymer film of polymethyl methacrylate (PMMA) by a laterally distributed electron beam is simulated with Monte Carlo calculations. The Monte Carlo simulation includes the significant contribution from electrons that are backscattered from the substrate (Si) into the film. Equienergy density contours (eV/cm3) are calculated for specific cases of beam voltage, film thickness, beam width, and beam‐edge slope. A time‐dependent solubility model is also incorporated to simulate the time evolution of the developed contours. A size effect is observed; i.e., the development time for a line depends on the line width. This intraproximity effect is ascribed to electrons backscattered from the substrate.
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79.20.Kz Other electron-impact emission phenomena
41.75.Fr Electron and positron beams
34.80.-i Electron and positron scattering

Distortion measurements in an electron image projector

J. P. Scott

J. Vac. Sci. Technol. 12, 1309 (1975); http://dx.doi.org/10.1116/1.568525 (4 pages) | Cited 2 times

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Distortion measurements in an electron image projector for integrated‐circuit fabrication are described. It is shown that the major cause of distortion which varies from exposure to exposure is due to slice bowing, and that this distortion is approximately 1/30 the height of the bow. This figure can be reduced by increasing the operating magnetic field strength.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Fr Electron and positron beams

Flatness, contrast, and resolution considerations of cathode projection microfabrication systems

G. A. Wardly

J. Vac. Sci. Technol. 12, 1313 (1975); http://dx.doi.org/10.1116/1.568526 (4 pages) | Cited 2 times

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’’Universal’’ edge‐resolution curves have been calculated for cathode‐projection microfabrication systems (CPS). The results show that submicron lithographic resolution requires photoemission energy spreads less than 100 ppm. This favors cesium iodide photocathodes which have up to a 0.5‐V energy spread. Exposure contrast in the CPS is made worse by a broad flood of reimpacting backscatter electrons. Furthermore, submicron edge‐resolution and registration capabilities of the CPS are made tenuous without a chucking device to hold the anode workpiece repeatably flat to about ±1 μm. Without flattening, performance can be impaired by image distortion and thermal effects.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
81.65.-b Surface treatments
41.75.Fr Electron and positron beams

Deep uv lithography

Burn Jeng Lin

J. Vac. Sci. Technol. 12, 1317 (1975); http://dx.doi.org/10.1116/1.568527 (4 pages) | Cited 17 times

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Using deep‐uv light ranging from 2000 to 2600 Å, submicrometer patterns in photoresist with height‐to‐width aspect ratios as high as 15 can be achieved. The well known electron‐beam positive resist, polymethyl methacrylate (PMMA), is used as the deep‐uv photoresist. Its optical absorption coefficient, dissolution rate, and sensitivity are given in the deep‐uv wavelength region. Its absorption coefficient, being a factor of two lower than that of AZ 1350J, makes it suitable for deep penetration of submicrometer‐wide beams. The negligible sensitivity at wavelengths longer than 2600 Å eliminates the need for an expensive filter. Both Xe–Hg arc lamps and deuterium spectral lamps have been used to expose the resist. Chrome or aluminum masks on quartz or sapphire substrates were found satisfactory. Chevron patterns of 1.6 μm width and 0.4 μm spacing and Y–I bars of 1.6 μm width and 0.2 μm gaps were printed in 3 μm of PMMA 2041, as well as Y–I bars of 0.5 μm width and 0.25 μm gaps in 1.78 μm of PMMA 2041. The exposure time in both cases was below 10 min.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
81.40.Tv Optical and dielectric properties related to treatment conditions

Prospects for x‐ray fabrication of Si IC devices

Henry I. Smith and S. E. Bernacki

J. Vac. Sci. Technol. 12, 1321 (1975); http://dx.doi.org/10.1116/1.568528 (3 pages) | Cited 2 times

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In this paper we report on low‐x‐ray‐attenuation Si vacuum windows for use with Al K x‐ray sources and the fabrication of 5.5‐cm‐diam Si‐membrane x‐ray masks without supporting ribs. Also discussed are exposure configurations for achieving multilevel pattern superposition on 7.5‐cm‐diam wafers.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
07.85.-m X- and γ-ray instruments

Abstract: New x‐ray mask of Al–Al2O3 structure

T. Funayama, Y. Takayama, T. Inagaki, and M. Nakamura

J. Vac. Sci. Technol. 12, 1324 (1975); http://dx.doi.org/10.1116/1.568529 (1 page)

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This paper describes the fabrication and performance of a newly developed x‐ray lithography mask consisting of an aluminum substrate and an Al2O3 film which was grown on the aluminum substrate by anodization. Transparent membranes of Al2O3 film were made by chemically etching parts of the aluminum substrate beneath the film on which gold absorber patterns were fabricated. Gold micropatterns were replicated successfully by Al Kα (8.34 Å) x rays. Properties of this mask include ease of fabrication, transparency, feasibility of realignment by optical means, and high mechanical strength allowing the capability of larger window size.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
07.85.-m X- and γ-ray instruments

Optimized source for x‐ray lithography of small area devices

Paul A. Sullivan and John H. McCoy

J. Vac. Sci. Technol. 12, 1325 (1975); http://dx.doi.org/10.1116/1.568530 (4 pages) | Cited 2 times

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The design and performance of an optimized soft‐x‐ray source using an air‐cooled Al target are described in this paper. The technical considerations leading to the choice of mask material, source wavelength, vacuum enclosure, and electron optics are also described. Although the authors have previously shown the need for large, powerful x‐ray sources, the source described here is intended for exposure of small‐area surface‐acoustic‐wave (SAW) devices with submicrometer dimensions. Since distortion over large areas need not be controlled, the x‐ray source is limited to 1 mm in diameter and the electron beam power to 250 W. A 25‐μm‐thick Be vacuum window was developed which made it possible to use the Al Kα x‐ray wavelength with a thin Si mask and yet maintain the exposure area in He at atmospheric pressure. The custom‐designed electron gun, exposure monitor, and thermal control system are also described. Results are reported on the replication of a SAW device pattern in PMMA resist with 0.5‐μm linewidths.
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07.85.-m X- and γ-ray instruments
41.75.Fr Electron and positron beams
85.40.Bh Computer-aided design of microcircuits; layout and modeling

Spurious effects caused by the continuous radiation and ejected electrons in x‐ray lithography

J. R. Maldonado, G. A. Coquin, D. Maydan, and S. Somekh

J. Vac. Sci. Technol. 12, 1329 (1975); http://dx.doi.org/10.1116/1.568531 (3 pages) | Cited 8 times

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X‐ray lithography replication using characteristic and continuous x radiation is studied and compared with exposure results obtained using only characteristic radiation. Several spurious effects that affect the mask contrast and system resolution are discussed.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
79.60.-i Photoemission and photoelectron spectra
07.85.-m X- and γ-ray instruments
41.75.Fr Electron and positron beams

Replication of 0.1‐μm geometries with x‐ray lithography

R. Feder, E. Spiller, and J. Topalian

J. Vac. Sci. Technol. 12, 1332 (1975); http://dx.doi.org/10.1116/1.568532 (4 pages) | Cited 10 times

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The effective range of secondary electrons generated by Al Kα radiation is measured in polymethylmethacrylate (PMMA) as 400 Å. Lines with 0.1‐μm linewidth with high aspect ratios are successfully replicated with x rays. Problems connected with the replication of very low contrast masks are discussed. Carbon Kα radiation is proposed as the radiation to be used for the replication of very fine geometries around or below 0.1 μm.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
79.60.-i Photoemission and photoelectron spectra
07.85.-m X- and γ-ray instruments
41.75.Fr Electron and positron beams

Microfabrication using laser‐beam interferometric technique coupled with simultaneous exposure and development method

Won‐Tien Tsang and Shyh Wang

J. Vac. Sci. Technol. 12, 1336 (1975); http://dx.doi.org/10.1116/1.568533 (4 pages)

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We have demonstrated the fabrication of two‐dimensional periodic arrays of shaped openings with uniform submicrometer to micrometer size and spacing over large areas in photoresist films coated on top of glass substrates using laser‐beam interferometric technique in conjunction with a simultaneous exposure and development (SED) method. The shapes of the openings obtained experimentally were compared with the theoretically calculated constant‐energy contours and found to be in good agreement. The two‐dimensional grating masks generated this way were shown to be comparable in quality with those generated by using computer‐controlled scanning‐electron‐beam (CCSEB) technique. Furthermore, the shape and size of the openings and the grid pattern can be conveniently varied. Most important of all is the fact that this technique is able to eliminate most of the disadvantages of the CCSEB technique.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
79.20.Ds Laser-beam impact phenomena

Comparison of the properties of different materials used as masks for ion‐beam etching

M. Cantagrel

J. Vac. Sci. Technol. 12, 1340 (1975); http://dx.doi.org/10.1116/1.568534 (4 pages) | Cited 3 times

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The different parameters used to describe the evolution of a step under ion‐beam etching are first defined. Then the properties of three different classes of masking materials are compared. It is concluded that the resists are not a useful high‐definition mask. Titanium and vanadium etched in an oxygen partial pressure give best results. Carbon is proposed as a third very interesting masking material due to the fact that its etching rate is high when bombarded with oxygen ions but low when bombarded with argon ions. The last part deals with the influence of ion‐beam incidence on the effective masking properties. Two examples are given: low periodicity gratings and overetching suppression at the bottom of steep edges.
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79.20.Rf Atomic, molecular, and ion beam impact and interactions with surfaces
85.40.Bh Computer-aided design of microcircuits; layout and modeling
41.75.Ak Positive-ion beams
41.75.Cn Negative-ion beams

Optimization of an electron‐bombardment ion source for ion machining applications

Paul D. Reader and Harold R. Kaufman

J. Vac. Sci. Technol. 12, 1344 (1975); http://dx.doi.org/10.1116/1.568535 (4 pages) | Cited 5 times

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A new 10‐cm‐diameter ion source has been designed specifically for ion machining applications. This source employs technology and experience from the development of ion engines for electron space propulsion and generates a highly uniform beam of 500‐eV Ar+ at current densities exceeding 2 mA/cm2.
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29.25.Lg Ion sources: polarized
29.25.Ni Ion sources: positive and negative
41.75.Ak Positive-ion beams
41.75.Cn Negative-ion beams
06.60.Vz Workshop procedures (welding, machining, lubrication, bearings, etc.)

Photoluminescence measurement of ion‐etched GaAs surface

S. Namba, M. Kawabe, N. Kanzaki, and K. Masuda

J. Vac. Sci. Technol. 12, 1348 (1975); http://dx.doi.org/10.1116/1.568536 (4 pages) | Cited 4 times

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The effects of ion etching and annealing of GaAs were studied by observing photoluminescence, reflectance, and electron diffraction patterns. The (100) surfaces of GaAs were rf sputter etched. The intensity of the edge emission decreased to about 1/15 of the initial value in the case of a Si‐doped sample when excited by a He–Cd laser (3250 Å) at 10 K. The depth of the damaged layer is deduced to exceed the bombarding ion range. Annealing increased the edge emission intensity up to the temperature of 450 °C, above which edge emission decreased due to thermal dissociation. On the other hand, electron diffraction patterns and reflection spectra showed continuous recovering of lattice ordering above the annealing temperature of 450 °C.
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61.80.Jh Ion radiation effects
61.80.Lj Atom and molecule irradiation effects
68.35.-p Solid surfaces and solid-solid interfaces: structure and energetics
85.40.-e Microelectronics: LSI, VLSI, ULSI; integrated circuit fabrication technology

Laser technique for the divestment of a lost Leonardo da Vinci mural

J. F. Asmus, D. L. Westlake, and H. T. Newton

J. Vac. Sci. Technol. 12, 1352 (1975); http://dx.doi.org/10.1116/1.568537 (4 pages) | Cited 2 times

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On 4 May 1504 Leonardo da Vinci was commissioned to paint a wall mural for the recently constructed Sala del Gran Consiglio adjacent to the Palazzo Vecchio of Florence. Several reports during the first half of the 16th century lauded this fresco (The Battle of Anghiari) as the most important sight in the city, and art historians suggest that it may have been Leonardo’s most significant work. Surprisingly, the mural was never again seen after the room was renovated in 1565. Recent investigative work has yielded evidence suggesting that the lost masterpiece may be intact somewhere on the large east wall of the present Salone dei Cinquecento, but walled‐in by substructures of the more modern Visari frescos. The probable delicate nature of the mural indicates that the removal of the final plaster covering without damaging the artwork may be exceedingly challenging. Consequently, we have been exploring a pulsed‐laser radiation technique that will accomplish selective vaporization of the plaster to reveal the surface of the Leonardo mural.
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89.20.Bb Industrial and technological research and development
79.20.Ds Laser-beam impact phenomena

Novel microfabrication process

S. M. Faris and T. K. Gustafson

J. Vac. Sci. Technol. 12, 1356 (1975); http://dx.doi.org/10.1116/1.568538 (3 pages)

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A process for fabricating metallic microstructures having submicron dimensions is discussed. Based on simple electrochemical etching of sputtered metallic strips on substrates, the process is potentially useful for making mechanically stable point‐contact devices.
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85.30.Hi Surface barrier, boundary, and point contact devices
81.65.Cf Surface cleaning, etching, patterning
81.65.Ps Polishing, grinding, surface finishing
82.45.-h Electrochemistry and electrophoresis

Mini magnetic lenses for microfocus x‐ray applications

L. A. Fontijn

J. Vac. Sci. Technol. 12, 1359 (1975); http://dx.doi.org/10.1116/1.568539 (4 pages)

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The mini magnetic lens is used to obtain a high‐definition x‐ray source positioned at the end of a long thin rod. This rod is the magnetic‐lens holder which has a useful length of 315 mm and an outer diameter of 10 mm. The x‐ray point source has a diameter of 0.1 mm providing a panoramic x‐ray pattern with an emergent beam angle of 45° in several elevation angles dependent on the x‐ray target configuration selected. Several 80‐ and 150‐kV microfocus x‐ray systems based on the mini‐magnetic‐lens construction are used for high‐definition nondestructive x‐ray inspection of small‐bore large‐depth welds as are found in heat exchangers for nuclear power stations.
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07.85.-m X- and γ-ray instruments
81.70.-q Methods of materials testing and analysis
07.07.-a General equipment

Abstract: Mass microanalyzer using electron‐beam guiding ion source

T. Takagi, I. Yamada, and T. Kishi

J. Vac. Sci. Technol. 12, 1363 (1975); http://dx.doi.org/10.1116/1.568540 (1 page) | Cited 2 times

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A new apparatus which performs microanalysis by analyzing ions evaporated from a specimen by the impact of a focused, scanned electron beam from an electron‐optical column which includes a ring cathode and electrostatic lenses is described. A model is developed that involves four steps:
(1) Material is locally evaporated from a specimen by bombardment with electrons of energy about 10 keV.
(2) The evaporated atoms are ionized by inelastic collisions with both primary and secondary electrons near the point of impact of the electron beam.
(3) The ions are trapped in the potential well (∠0.1–1 eV) formed by the electron beam.
(4) The ions are accelerated through the electron‐optical column toward the entrance slit of the mass spectrometer and are mass analyzed.
The model predicts that for a primary electron current Ie, the collected ion current Ii is equal to (2m/M) Ie or 4×10−8 A for N2 ions and Ie=1 mA. For high beam currents (1 mA), the spatial resolution of the system was demonstrated to be less than 1 mm. The ultimate spatial resolution of the system is estimated to be 1 μm with the removal of 44 atom layers from the specimen; this estimate is based on a minimum detectable ion current of 10−16 A and a collection angle of 10−2 rad.
Experimental results were obtained from a specimen of evaporated NaCl on stainless steel. The preliminary experiments demonstrate the possible use of this instrument for surface analysis and the theory indicates the technique could provide micron spatial resolution.
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07.75.+h Mass spectrometers
06.30.Dr Mass and density
41.75.Fr Electron and positron beams

Abstract: Scanning microspot Auger spectroscopy and microscopy as a device diagnostic technique

A. Christou and H. M. Day

J. Vac. Sci. Technol. 12, 1363 (1975); http://dx.doi.org/10.1116/1.568541 (1 page)

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Auger spectroscopy with a focused electron beam in the scanning electron microscope (SEM) has been applied as a diagnostic technique for solid state devices. The focused electron beam in a SEM allows one to determine the surface topography (SEM mode) of the specimen and then determine the Auger spectra of selected areas. In addition, a scanning Auger image may be obtained by using the amplitudes of the Auger peaks for intensity or amplitude modulation of the cathode ray tube. In the present system, a SEM designed with a dry‐pump UHV system and equipped with an Auger electron detector and sputter etching capability has been applied to device failure diagnostics. Vacuum levels of 3×10−9 Torr (4×10−7 Pa) at the specimen stage have been obtained with an electro‐ion‐titanium sublimation pumping system. A secondary electron image resolution of less than 2000 Å with Auger spectra of features less than 1 μm have been attained. Gray‐scale images from Auger electrons have been obtained at beam currents of 10−6 to 10−8 A. The Auger electron detector used has an energy resolution of 0.5% and transmission of 10%. A sputter‐etching capability for sputter cleaning of specimen surfaces prior to analysis is provided.
The energy source of the SEM is a triode electron gun with a high‐emission filament (3.5×105 A cm−2 sr−1 at 20 kV). The relationship between probe current and diameter for a fixed working distance was measured in order to determine the optimum spatial resolution for AES. For optimum conditions and high beam currents (10−6 A) spatial resolution is essentially determined by the probe diameter. For low beam currents, it is shown that parameters such as escape depth, atomic number, surface area, and beam energy affect spatial resolution. AES recording time and its variation with signal‐to‐noise ratio has also been determined.
The normal modes for microspot AES investigations in the SEM include spot analysis, line scan, and Auger electron imaging. For Auger imaging the vacuum levels and probe currents are shown to be the critical parameters since the time to record such an image is usually greater than five minutes.
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85.30.De Semiconductor-device characterization, design, and modeling
68.35.-p Solid surfaces and solid-solid interfaces: structure and energetics
07.78.+s Electron, positron, and ion microscopes; electron diffractometers
79.20.Fv Electron impact: Auger emission

High‐spatial‐resolution scanning Auger spectroscopy applied to analysis of X‐band diode burnout

W. H. Weisenberger, A. Christou, and Y. Anand

J. Vac. Sci. Technol. 12, 1365 (1975); http://dx.doi.org/10.1116/1.568542 (4 pages)

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Low‐noise‐figure Schottky‐barrier mixer diodes for use at X‐band and above have small active areas and are thus susceptible to burnout or degradation from high rf power levels. As part of a program to improve burnout resistance of mixer diodes for a Navy system, metal diffusion couples were studied and diodes were fabricated, burned out, and analyzed. The microspot Auger analysis technique in the Auger‐spot mode provided the required submicron identification of the interdiffusion phenomena in the failed regions of the mixer diodes. For cw‐failed diodes, interdiffusion between the various diffusion couples found in both Pt–Ti–Mo–Au and Ti–Mo–Au diodes has been identified as the primary failure mode. In the pulsed case the lack of interdiffusion as made evident in the analysis of edge‐burned‐out sites indicates the existence of an alternate failure mode.
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85.30.Hi Surface barrier, boundary, and point contact devices
84.30.Qi Modulators and demodulators; discriminators, comparators, mixers, limiters, and compressors
73.30.+y Surface double layers, Schottky barriers, and work functions

Penning source for ion implantation

J. P. Flemming

J. Vac. Sci. Technol. 12, 1369 (1975); http://dx.doi.org/10.1116/1.568543 (4 pages)

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A cold‐cathode Penning‐type ion source with axial extraction has been developed to provide the milliampere ion currents needed for high volume, high throughput ion implantation. For solid feed material, the source is fitted with an oven that is concentric with the anode. The oven windings heat the anode to prevent condensation of feed vapor in the source. The ion beam is extracted through a three‐element electrode assembly which provides lens action. The optical effect of space‐charge forces completes beam formation. The output consists of up to 12 mA ion current in the form of a beam that is parallel to better than 10 mR and of diameter less than 2.5 cm. The beam contains 15% boron, 30% phosphorus, 50% arsenic when the source is run on BF3, 10% PH3, or solid arsenic. The source allows analyzed currents in the 1–3‐mA range to be produced for periods of about 40 h.
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61.72.U- Doping and impurity implantation
29.25.Lg Ion sources: polarized
29.25.Ni Ion sources: positive and negative

Abstract: Determination of ion‐implanted profiles using the MOS capacitance–voltage technique

J. R. Edwards and G. Marr

J. Vac. Sci. Technol. 12, 1373 (1975); http://dx.doi.org/10.1116/1.568544 (1 page) | Cited 1 time

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In this paper, the application of the MOS capacitance–voltage technique for the determination of ion‐implanted impurity profiles is described experimentally and theoretically for moderate (1011–1012 ions/cm2) ion implants.
The experimental vehicle was a large‐geometry p‐channel IGFET (250×250 μm) which was implanted with boron ions at an energy of 120 keV through the gate region (500 Å Al2O3 + 1000 Å SiO2). This results in a doping profile with a peak approximately 1700 Å beneath the Si–SiO2 interface and an effective Debye length the order of 500 Å. Since the application of a gate voltage results in a maximum surface depletion width which is less than the boron profile depth, a reverse bias was applied between the source‐drain diffusions and the substrate in order to sweep out the inversion electrons that otherwise would shield the surface electric field. The resulting gate to source‐drain capacitance curve in the surface depletion region was used to determine the implanted profile with the Kennedy–O’Brien majority carrier correction factor included. This was also compared to a theoretical Gaussian implant profile based on theoretical values for range and straggle.
To examine the validity of the experimental results, a theoretical study was made using the following method: (1) Assume a Gaussian profile. (2) From the above, calculate the semiconductor capacitance. (3) Use the capacitance to calculate an ’’effective’’ profile. (4) Compare the ’’effective’’ profile with the Gaussian profile. This comparison showed that the measured profile can be determined with resolution substantially less than a Debye length.
Based on this work, it is concluded that the substrate‐biased MOS transistor capacitance of an ion‐implanted depletion‐mode IGFET is a practical method which can be used for process control of the peak of the implant to an accuracy which is better than a Debye length.
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61.72.sd Impurity concentration
61.72.sh Impurity distribution
61.72.sm Impurity gradients
81.05.Dz II-VI semiconductors
81.05.Ea III-V semiconductors
85.30.Tv Field effect devices

Channeling ion implantation through palladium films

Hiroshi Ishiwara and Seijiro Furukawa

J. Vac. Sci. Technol. 12, 1374 (1975); http://dx.doi.org/10.1116/1.568545 (4 pages) | Cited 2 times

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The possibility of channeling ion implantation into semiconductors through polycrystalline metallic layers is studied. Minimum values and standard deviations of channeling angular yield in polycrystalline Pd2Si layers formed on Si have been measured by protons and 4He, and 14N ion backscattering and channeling measurements. Depth distributions of the spread of crystallite orientations and scattering centers such as lattice defects have been separately derived by using the above two quantities. It has been concluded that the channeling‐ion‐implantation technique will become a practical one by using the parallel scanning system.
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61.72.U- Doping and impurity implantation
61.85.+p Channeling phenomena (blocking, energy loss, etc.)

Fabrication of lateral doping profiles by a computer‐controlled focused ion beam

R. L. Seliger and J. W. Ward

J. Vac. Sci. Technol. 12, 1378 (1975); http://dx.doi.org/10.1116/1.568546 (4 pages) | Cited 1 time

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The advantages and throughput of a specialized focused‐ion‐beam technique—the creation of smoothly varying lateral doping profiles—are investigated. Calculated and experimental results are presented for the technique by which the log(gain) –gate‐voltage characteristic of a GaAs FET can be linearized over four orders of magnitude. The throughput of the lateral tailoring process is estimated to exceed 1000 devices per hour based on the assumptions of a 10‐mil2 (640‐μm2) area per device, an average tailoring dose of 1012 ions/cm2 for a 5‐μm‐diam focused spot, an ion beam brightness of ∠50 A cm‐2 sr for dopant ions at typical implantation voltages 50–150 kV, and a total overhead (i.e., positioning and registration) time of 1 sec per device. While a focused ion beam system with these capabilities will require development, the performance requirements including the ion‐source brightness are well within the scope of present technology.
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85.40.Bh Computer-aided design of microcircuits; layout and modeling
61.72.U- Doping and impurity implantation
85.30.Tv Field effect devices
41.75.Ak Positive-ion beams
41.75.Cn Negative-ion beams

Abstract: Positive photoresist masking properties of high energy, high dose phosphorous‐ion implants and their influence on MOS FET device characteristics

J. M. Mayone, G. M. Oleszek, and O. S. Spencer

J. Vac. Sci. Technol. 12, 1382 (1975); http://dx.doi.org/10.1116/1.568547 (1 page)

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The use of a positive photoresist (PR) as a phosphorus‐ion implant mask for defining the source and drain of a MOS FET suffers from outgassing and deformation of the resist when high energy ions (150 keV) and a high dose (5×1015 P+/cm2) are involved. This deformation affects the dose uniformity and MOS FET channel length. Here we compare PR masks with those made up of a baked mixture of photoresist and a thermal free radical (PR+TFR) as suggested by Kluge and Elie.1 During the preimplant bake the thermoplastic deformation of the PR+TFR mask is significantly lower than that of the PR mask, but there is no significant difference between the deformation of the two masks during implantation providing the preimplantation bakes are the same. We have made MOS FET’s with channel length as defined by the mask (Lmask) varying from 0.15 to 1.600 mil(3.8 to 4 μm) and have visually measured Lmask following the preimplantation bake. By measuring the MOS FET characteristics (in the linear region) we can determine the effective channel length and compare this with Lmask over a wide range of values. The deformation of the resist can be reduced by using thinner resist and be made negligible by substituting low temperature vacuum baking (prior to implantation) for the conventional high temperature air bake.
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85.30.Tv Field effect devices
61.72.U- Doping and impurity implantation

Properties of superconducting weak links produced by ion implantation

E. P. Harris

J. Vac. Sci. Technol. 12, 1383 (1975); http://dx.doi.org/10.1116/1.568548 (4 pages) | Cited 2 times

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A new technique has been developed for making superconducting weak links, making use of the fact that the superconducting transition temperature (Tc) of certain metals (e.g., W, Mo) can be greatly increased by ion implantation. By implanting controlled patterns of N+ and S+ ions into Mo films, structures have been produced in which two heavily doped Mo regions with high Tc are joined by a short (≲1 μm) lightly doped Mo region with lower Tc which acts as a weak link. These rugged and stable structures display the ac and dc Josephson effects. These techniques lend themselves to the production of superconducting integrated circuits containing weak links.
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85.40.-e Microelectronics: LSI, VLSI, ULSI; integrated circuit fabrication technology
74.78.-w Superconducting films and low-dimensional structures
85.25.-j Superconducting devices
85.25.Dq Superconducting quantum interference devices (SQUIDs)

Ion milling (ion‐beam etching), 1954–1975: A bibliography

Donald T. Hawkins

J. Vac. Sci. Technol. 12, 1389 (1975); http://dx.doi.org/10.1116/1.568549 (10 pages) | Cited 5 times

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The ion milling process is briefly described as an introduction to the extensive bibliography presented on this process and its varied applications. (AIP)
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79.20.-m Impact phenomena (including electron spectra and sputtering)
81.65.Cf Surface cleaning, etching, patterning